Materials and Device Modeling and Simulation

Simulation of nanostructure-based and ultra-thin film solar cell devices beyond the classical picture

[+] Author Affiliations
Urs Aeberhard

IEK-5 Photovoltaik, Forschungszentrum Jülich, Jülich D-52425, Germany

J. Photon. Energy. 4(1), 042099 (Aug 21, 2014). doi:10.1117/1.JPE.4.042099
History: Received April 11, 2014; Revised July 15, 2014; Accepted July 30, 2014
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Abstract.  An optoelectronic device simulation framework valid for arbitrary spatial variation of electronic potentials and optical modes, and for transport regimes ranging from ballistic to diffusive, is used to study the nonlocal photon absorption, photocurrent generation and carrier extraction in ultra-thin film, and nanostructure-based solar cell devices at the radiative limit. Among the effects that are revealed by the microscopic approach and which are inaccessible to macroscopic models is the impact of structure, doping- or bias-induced nanoscale potential variations on the local photogeneration rate and the photocarrier transport regime.

Figures in this Article

Since the introduction of novel light-trapping schemes reaching beyond the ray-optics limit, high-efficiency solar cells with an active absorber thickness of only a fraction of the typical irradiation wavelength are becoming interesting alternatives to expensive wafer-based architecture. In the case where these ultra-thin film solar cells are made of high-mobility semiconductors, the classical picture of local charge carrier generation and diffusive transport in thermalized distributions may no longer be appropriate, especially in the presence of strong doping-induced internal fields. The same applies to a wide range of nanostructure-based photovoltaic device components, such as quantum well and quantum dot structures or highly doped tunnel junctions, in which the local electronic structure deviates strongly from the flat band bulk picture conventionally assumed in photovoltaic device simulations.

In this situation, microscopic theories on the quantum kinetic level allow for the step beyond the local and macroscopic description by enabling the consideration of arbitrary potential variations and general nonequilibrium carrier distributions at the nanoscale. For the specific case of photovoltaic devices, where optical transitions and charge carrier transport are equally important, such a theory has recently been formulated based on the nonequilibrium Green’s function formalism (NEGF) and has been successfully applied to the investigation of a number of nanostructure-based solar cell architectures.15

In the present study, the focus is on the impact of structure, doping- or bias-induced nanoscale potential variations on the local photogeneration rate and the photocarrier transport regime, as these features are not accessible in macroscopic approaches.6

The general NEGF theory of nanostructure-based solar cell devices is described in detail in 7. Here, only the elements relevant for the current investigation will be presented. In consideration of the high computational cost associated with the NEGF simulation approach, the current application of the formalism is restricted to the technologically most relevant class of thin-film devices containing planar nanostructures.

Green’s Functions and Self-Energies for Planar Systems

In the case of planar device architectures, the charge carriers are described by a slab representation for the steady-state Green’s functions (GFs), Display Formula

G(r,r,E)=A1kG(k,z,z,E)eik·(rr),(1)
where A is the slab cross-sectional area. The classical electromagnetic field is expressed via the vector potential Display Formula
A(r,t)=A12qA(q,z,t)eiq·r.(2)

The steady-state charge carrier GF is obtained from the integro-differential equations Display Formula

GR(k,z,z,E)=G0R(k,z,z,E)+dz1dz2G0R(k,z,z1,E)ΣR(k,z1,z2,E)GR(k,z2,z,E),(3)
Display Formula
G(k,z,z,E)=dz1dz2GR(k,z,z1,E)Σ(k,z1,z2,E)GA(k,z2,z,E),(4)
with Display Formula
[EH0(k,z)]G0R(k,z,z,E)=δ(zz).(5)

The noninteracting part H^0 of the Hamiltonian contains the electronic structure (at this stage, a simple two-band effective mass model) and the electrostatic mean-field potential from coupling to the Poisson equation via the nonequilibrium carrier densities, Display Formula

n(z)=A1kdE2π[iGcc<(k,z,z,E)],p(z)=A1kdE2π[iGvv>(k,z,z,E)].(6)

The term H^eγ=(e/m0)A^(r,t)·p^ is used to describe the interaction of charge carriers with photons that are required for radiative generation and recombination processes via corresponding nonlocal self-energies, e.g., for electrons in the conduction band, Display Formula

Σcc<(gen)(k,z,z,E)=(em0)2μpcvμ(z)pcvμ*(z)dEγGvv<(k,z,z,EEγ)A1qAμ(q,z,Eγ)Aμ*(q,z,Eγ),(7)
Display Formula
Σcc>(rec)(k,z,z,E)=(em0)2μ,νpcvμ(z)pcvν*(z)dEγ2πGvv>(k,z,z,EEγ)A1qiμ0Dμν>(q,z,z,Eγ),(8)
Display Formula
n036π2c03ε0(em0)2μpcvμ(z)pcvμ*(z)dEγEγGvv>(k,z,z,EEγ),(9)
where the local approximation of the momentum-averaged GF of free field photon modes, Display Formula
A1qDμν,0>(q,z,z,Eγ)in03Eγ3πc0δμν,(zz),(10)
was used in the last line. This corresponds to emission into an optically homogeneous medium. The classical electromagnetic vector potential A in the multilayer device is obtained from the conventional transfer matrix method (TMM). The local extinction coefficient used in the TMM is related to the local absorption coefficient as obtained from the microscopic interband polarization in terms of the charge carrier GFs.8 At this point, it should be noted that for detailed balance to hold, both self-energies should be expressed in terms of the same photon GF, which can be obtained from an additional set of Dyson and Keldysh equations similar to Eqs. (3) and (4).9

In addition to the electron–photon interaction, the coupling of charge carriers to phonons also needs to be considered for the description of relaxation effects and phonon-mediated transport processes. Here, it is included via the standard self-energy on the level of the self-consistent Born approximation based on the noninteracting equilibrium GFs of bulk phonon modes.10

Absorption, Generation Rate, and Photocurrent

The local and spectral photogeneration rate g at fixed photon energy (Eγ), polarization (μ), and incident angle (q, Eγ), where q is the transverse photon momentum, is related to the corresponding local absorption coefficient α and local photon flux Φ via Display Formula

gμ(q,z,Eγ)=Φμ(q,z,Eγ)αμ(q,z,Eγ).(11)

In the NEGF formalism, the spectral photogeneration rate can be obtained from the expression for the local integral radiative interband generation rate G in terms of electronic GFs and self-energies,8 which for charge carriers in the conduction band reads Display Formula

Gc(z)=A1kdzdE2πΣcc<(gen)(k,z,z,E)Gcc>(k,z,z,E)A1μqdEγgcμ(q,z,Eγ).(12)

At the radiative limit, the short-circuit current density Jsc is directly given by the incident photon flux and the total absorptance of the slab, Display Formula

Jsc=eAqdEγΦ(q,z0,Eγ)·a(q,zmax,Eγ).(13)

On the other hand, the recombination-free limit of the short-circuit current derives from the quantities computed within the NEGF formalism as follows:8Display Formula

Jsc=jc(zmax)jc(z0)=z0zmaxdzzj(z)ez0zmaxdzGc(z),(14)
where jc denotes the electron current in the conduction band, which is given in terms of the charge carrier GFs via Display Formula
jc(z)=limzzem0(zz)A1kdE2πGcc<(k,z,z,E).(15)

Together, Eqs. (12)–(14) yield the following expression of the absorptance in terms of the local generation spectrum: Display Formula

aμ(q,zmax,Eγ)=Φμ1(q,z0,Eγ)z0zmaxdzgμ(q,z,Eγ).(16)

Using the electron–photon self-energy (7) in Eq. (12) for G, the local spectral photogeneration acquires the following form: Display Formula

gμ(q,z,Eγ)=iμ0Aμ(q,z,Eγ)dzAμ*(q,z,Eγ)Πμμ>(q,z,z,Eγ),(17)
where Π is the photon self-energy related to the nonequilibrium polarization function P and the momentum matrix elements pcv, Display Formula
Πμν>(q,z,z,Eγ)=iμ0(em0)2pcvμ*(z)Pcv>(q,z,z,Eγ)pcvν(z),(18)
with the random-phase approximation of the interband polarization function given in terms of the charge carrier GFs as follows: Display Formula
Pcv>(q,z,z,Eγ)=A1kdE2πGcc>(k,z,z,E)Gvv<(kq,z,z,EEγ).(19)

Using Eq. (17) in Eq. (16), the final expression for the absorptance of a slab of thickness d=zmaxz0 acquires the form Display Formula

aμ(q,zmax,Eγ)=iμ0Φμ1(q,z0,Eγ)z0zmaxdzz0zmaxdzAμ(q,z,Eγ)Aμ*(q,z,Eγ)Πμμ>(q,z,z,Eγ).(20)

The local absorption coefficient α that is required to provide the extinction coefficient Display Formula

κμ(q,z,Eγ)=αμ(q,z,Eγ)·c02Eγ(21)
used in the TMM is formally defined by Eq. (11) in terms of the local values of photon flux and photogeneration. If the local variation of the electromagnetic field is neglected, an expression can be found that contains solely the local electronic properties, Display Formula
αμ(q,z,Eγ)=c02nr(q,z,Eγ)EγdzRe[iΠμμ>(q,z,z,Eγ)].(22)

Recombination and Radiative Dark Current

In analogy to the photogeneration process, a local rate of radiative recombination can be expressed in terms of the emission self-energy and carrier GF, Display Formula

Rc(z)=A1kdzdE2πΣcc>(rec)(k,z,z,E)Gcc<(k,z,z,E)A1μqdEγrcμ(q,z,Eγ),(23)
which defines the transverse momentum average of the local and spectral radiative emission rate r¯, Display Formula
r¯cμ(z,Eγ)A1qrcμ(q,z,Eγ)n03Eγ6π22c0dzRe[iΠμμ<(0,z,z,Eγ)],(24)
where the photon self-energy component Π< is given by Eq. (18) with “>” replaced by “<”. The radiative dark current is obtained as the spatial integral of the local recombination rate, Display Formula
Jdark,rad=ez0zmaxdzRc(z).(25)

In the following, deviations from the bulk or flat-band picture are revealed by applying the above formalism to specific structures encountered as components of advanced nanostructure-based solar cell architectures, such as ultra-thin films, superlattices, and heterostructure tunnel junctions. In all cases, the electronic structure is described by a simple two- band model of a direct semiconductor, using either the effective mass approximation (EMA) or an spz tight-binding (TB) approach, with parameters given in Table 1 (EMA) or in 5 (TB). Intraband relaxation and energy dissipation are considered via inclusion of inelastic coupling of charge carriers to a single polar optical phonon mode as well as elastic coupling to acoustic phonons, and the extinction coefficient used for the light propagation is computed according to the local approximation in Eq. (22).

Table Grahic Jump Location
Table 1Material parameters for the two-band effective mass model used for the simulation of the ultra-thin film and quantum well superlattice absorbers.
Field-Dependent Generation and Recombination in Ultra-Thin Film Absorber Solar Cells

Recently, plasmonic concepts were presented for strong confinement of the incident light in absorber layers with thickness of only a few nm.11,12 If such ultra-thin film solar cells remain based on bipolar junctions, such as the 40 nm GaAs pin diode with doping density of 3×1018cm3 investigated here using the EMA with parameters given in Table 1, the doping-induced built-in potential is dropped over a very short distance (Fig. 1), which results in strong doping- and bias-dependent band tailing (Franz–Keldysh) effects on the absorptance (Fig. 2), and consequently on the shape of the monochromatic current–voltage characteristics (Fig. 3). The bias-dependent band tail leads not only to subgap absorption, but also to a red shifting of the emission spectra under electrical injection at forward bias (Fig. 4). The decrease of the field with increasing bias causes the ideality factor of the radiative dark current to shrink toward unity as the field-induced tunnel enhancement of the recombination process is reduced (Fig. 5).

Graphic Jump LocationF1 :

Band profile and local density of states of a 40-nm GaAs pin junction solar cell. The doped layers extend over 10 nm and provide a charge carrier density of 3×1018cm3.

Graphic Jump LocationF2 :

The strong built-in potential present in the ultra-thin junction leads to a Franz–Keldysh tailing of the band edge, inducing the absorption of sub-bandgap energy photons. Following the strength of the built-in field, the tailing (a) increases with doping density and (b) decreases with forward bias. The effect on the absorptance depends on the photon energy, whereas the absorption is increased at sub-bandgap energies, it is reduced above the band edge.

Graphic Jump LocationF3 :

The bias dependence of the absorptance at different photon energies as displayed in Fig. 2 is reflected in the monochromatic current–voltage characteristics (@0.1kW/cm2).

Graphic Jump LocationF4 :

With the field-induced extension of the band edge to lower energies, the emission is also redshifted.

Graphic Jump LocationF5 :

The characteristics of the radiative dark current show a tunnel enhancement of the ideality factor, which decreases as the field is reduced.

Photocarrier Transport in Quantum Well Superlattice Solar Cells

Quantum well superlattice solar cells were proposed some time ago as tunable bandgap absorber components in multijunction solar cells.13 Recently, absorber structures with strongly coupled quantum wells have shown enhanced carrier extraction efficiency as compared with multiquantum well structures with decoupled wells.14 Conventional approaches to the simulation of quantum well superlattice solar cells assume either an infinite superlattice at flat band conditions and band-like semiclassical transport15 or ballistic transport via the transfer matrix formalism.16

Here, we use again the two-band EMA-NEGF approach. Figure 6 shows the local density of states of a 20 period, selectively contacted In0.52Al0.33Ga0.15As-In0.53Ga0.47As quantum well superlattice with barrier and well thicknesses of 1.5 and 2.5 nm, respectively, for (a) the flat band situation, corresponding to an intrinsic system and (b) a pin structure with strong built-in field induced by a doping density of 2×1018cm3. The strong coupling of the quantum wells results in a bulk-like density of states, however, exhibiting an confinement-induced increase in the effective bandgap as compared with bulk InGaAs. Both features are preserved in the presence of the large built-in field.

Graphic Jump LocationF6 :

Local density of states of a 20-period quantum well superlattice at vanishing bias voltage and (a) flat band conditions, corresponding to an intrinsic system, and (b) for a doping density of 2×1018cm3. Although the effective bandgap is increased as compared with bulk InGaAs because of confinement, the strong coupling results in a pronounced carrier delocalization and associated quasi-3D DOS.

The (radiative) current–voltage characteristics of the 20-period superlattice structure are displayed in Fig. 7 for applied forward bias voltage in the dark and under monochromatic illumination with photons of an energy of 0.95 eV and at an intensity of 0.1kW/cm2. The current–voltage characteristics J(V) under illumination are perfectly reproduced by the superposition of the bias-dependent photocurrent Jabs(V) as computed from the absorptance and the radiative dark current Jdark(V). Therefore, the charge carrier collection probability is close to unity even at large bias voltages in the vicinity of the maximum power point.

Graphic Jump LocationF7 :

Current voltage characteristics of the 20-period superlattice in the dark and under monochromatic illumination with photons of 0.95 eV and at 0.1kW/cm2. Because of the high degree of delocalization, the carrier escape probability is unity, i.e., the light JV-curve is the exact superposition of the bias-dependent photocurrent from the absorptance and the radiative dark current.

The charge carrier extraction can be investigated in more detail by considering the (spectral) current flow at different bias voltages. Figure 8 shows the current–voltage characteristics together with spectral and integral current flow, for (a) short-circuit conditions (0 V), (b) close to the maximum power point (0.45 V), (c) at open-circuit conditions (0.52 V), and (d) at open-circuit voltage in the dark. The sum of integral electron and hole currents is conserved at all bias voltages. As can be inferred from the current spectra, the minibands break up under realistic built-in fields, but at strong coupling, i.e., for thin barriers, carrier extraction proceeds almost ballistically. However, as shown in Fig. 9 for the structures of coupled 2.5-nm wide InGaAs with InAlGaAs barriers of thickness increasing from 1.5 to 3.5 nm, for thick barriers, the character of carrier transport changes from ballistic to sequential tunneling assisted by phonon-mediated relaxation. Thus, a rigorous assessment of carrier extraction in a given superlattice structure under realistic operating conditions is only provided at the quantum kinetic level.

Graphic Jump LocationF8 :

JV characteristics, integral and spectral current flow at (a) short-circuit conditions (0 V), (b) close to the maximum power point (0.45 V), (c) at open-circuit conditions (0.52 V), and (d) at open-circuit voltage in the dark. Although the minibands break up under realistic built-in fields, carrier extraction proceeds almost ballistically for thin barriers.

Graphic Jump LocationF9 :

Photocurrent spectrum (0.1kW/cm2@0.95 eV) of coupled quantum well absorber structures with fixed InGaAs QW size of 2.5 nm and InAlGaAs layer thicknesses ranging from 1.5 to 3.5 nm. With increasing barrier width, the character of carrier transport gradually changes from quasi-ballistic to phonon-assisted sequential tunneling.

Absorption Losses in Double Quantum Well Tunnel Junctions for Multijunction Solar Cells

In high-efficiency multijunction solar cells, double quantum well structures have been proposed as tunnel junctions with high peak currents as well as low optical transmission losses.17 In the junction region, the pronounced spatial variation of the doping profile gives rise to extreme band bending effects. As shown by recent NEGF simulations employing a spz tight-binding basis,5 the strong fields result in large deviations of the local density of states from the situation at flat band conditions, apparent in both bulk injection and quantum well tunnel zones [Fig. 10(a)]. The local structure of bound and quasibound states in the junction region not only affects the tunneling transport of charge carriers, but also affects the local absorption coefficient [Fig. 10(b)]. The associated absorptance no longer reflects the joint density of states of either the bulk injection regions or a regular square well potential [Fig. 10(c)].

Graphic Jump LocationF10 :

(a) Local density of states in a double quantum well tunnel junction, (b) associated local absorption coefficient, and (c) the overall absorptance of the structure, revealing pronounced deviations from the flat band situation of a square well potential and bulk injection regions.

The strong local potential variations that are present in ultra-thin or nanostructure-based solar cell devices have a large impact on the photogeneration, photocarrier extraction, and radiative recombination processes, which is fully captured by the proposed NEGF-based simulation framework. Notable examples are strong field-induced band tailing effects in ultra-thin junction solar cells, with associated red shift in the absorption and emission spectra. It is further shown that the deviations from the flat band bulk picture are of special relevance for the assessment of carrier transport in superlattice solar cells and of the absorption losses in novel tunnel junction architectures for multijunction devices.

Aeberhard  U., Morf  R. H., “Microscopic nonequilibrium theory of quantum well solar cells,” Phys. Rev. B. 77, (12 ), 125343  (2008). 1098-0121 CrossRef
Aeberhard  U., “Theory and simulation of photogeneration and transport in Si-SiOx superlattice absorbers,” Nanoscale Res. Lett.. 6, , 242  (2011). 1556-276X CrossRef
Aeberhard  U., “Effective microscopic theory of quantum dot superlattice solar cells,” Opt. Quantum Electron.. 44, (3–5 ), 133 –140 (2012). 0306-8919 CrossRef
Aeberhard  U. et al., “Fluorescence of colloidal PbSe/PbS QDs in NIR luminescent solar concentrators,” Phys. Chem. Chem. Phys.. 14, (47 ), 16223 –16228 (2012). 1463-9076 CrossRef
Aeberhard  U., “Theoretical investigation of direct and phonon-assisted tunneling currents in InAlGaAs/InGaAs bulk and quantum-well interband tunnel junctions for multijunction solar cells,” Phys. Rev. B. 87, (8 ), 081302  (2013). 1098-0121 CrossRef
Aeberhard  U., “Simulation of absorption, photogeneration, and carrier extraction in nanostructure-based and ultra-thin film solar cell devices beyond the classical picture,” Proc. SPIE. 8981, , 898103  (2014). 0277-786X CrossRef
Aeberhard  U., “Theory and simulation of quantum photovoltaic devices based on the non-equilibrium Green’s function formalism,” J. Comput. Electron.. 10, (4 ), 394 –413 (2011). 1569-8025 CrossRef
Aeberhard  U., “Quantum-kinetic theory of photocurrent generation via direct and phonon-mediated optical transitions,” Phys. Rev. B. 84, (3 ), 035454  (2011). 1098-0121 CrossRef
Aeberhard  U., “Photon Green’s functions for a consistent theory of absorption and emission in nanostructure-based solar cell devices,” Opt. Quantum Electron.. 46, (6 ), 791 –796 (2014). 0306-8919 CrossRef
Mahan  G., “Quantum transport equation for electric and magnetic fields,” Phys. Rep.. 145, (5 ), 251 –318 (1987). 0370-1573 CrossRef
Massiot  I. et al., “Nanopatterned front contact for broadband absorption in ultra-thin amorphous silicon solar cells,” Appl. Phys. Lett.. 101, (16 ), 163901  (2012). 0003-6951 CrossRef
Wang  Z., White  T. P., Catchpole  K., “Plasmonic near-field enhancement for planar ultra-thin photovoltaics,” IEEE Photon. J.. 5, (5 ), 8400608  (2013).CrossRef
Green  M. A., “Potential for low dimensional structures in photovoltaics,” Mat. Sci. Eng. B. 74, (1–3 ), 118 –124 (2000). 0921-5107 CrossRef
Fujii  H. et al., “100-period, 1.23-eV bandgap InGaAs/GaAsP quantum wells for high-efficiency GaAs solar cells: toward current-matched Ge-based tandem cells,” Prog. Photovolt: Res. Appl.. 22, (7 ), 784 –795 (2014). 1062-7995 CrossRef
Kirchartz  T. et al., “Efficiency limits of Si/SiO2 quantum well solar cells from first-principles calculations,” J. Appl. Phys.. 105, (10 ), 104511  (2009). 0021-8979 CrossRef
Courel  M., Rimada  J. C., Hernández  L., “GaAs/GaInNAs quantum well and superlattice solar cell,” Appl. Phys. Lett.. 100, (7 ), 073508  (2012). 0003-6951 CrossRef
Lumb  M. P. et al., “Double quantum-well tunnel junctions with high peak tunnel currents and low absorption for InP multijunction solar cells,” Appl. Phys. Lett.. 100, (21 ), 213907  (2012). 0003-6951 CrossRef

Urs Aeberhard is a senior researcher at the Institute of Energy and Climate Research 5: Photovoltaics, Research Centre Jülich, Germany. He received a diploma degree in theoretical physics and PhD degree in condensed matter theory from the Swiss Federal Institute of Technology in Zurich (ETHZ) in 2004 and 2008, respectively. His current research interests include the theory and simulation of nanostructure-based solar cell devices.

© The Authors. Published by SPIE under a Creative Commons Attribution 3.0 Unported License. Distribution or reproduction of this work in whole or in part requires full attribution of the original publication, including its DOI.

Citation

Urs Aeberhard
"Simulation of nanostructure-based and ultra-thin film solar cell devices beyond the classical picture", J. Photon. Energy. 4(1), 042099 (Aug 21, 2014). ; http://dx.doi.org/10.1117/1.JPE.4.042099


Figures

Graphic Jump LocationF1 :

Band profile and local density of states of a 40-nm GaAs pin junction solar cell. The doped layers extend over 10 nm and provide a charge carrier density of 3×1018cm3.

Graphic Jump LocationF2 :

The strong built-in potential present in the ultra-thin junction leads to a Franz–Keldysh tailing of the band edge, inducing the absorption of sub-bandgap energy photons. Following the strength of the built-in field, the tailing (a) increases with doping density and (b) decreases with forward bias. The effect on the absorptance depends on the photon energy, whereas the absorption is increased at sub-bandgap energies, it is reduced above the band edge.

Graphic Jump LocationF3 :

The bias dependence of the absorptance at different photon energies as displayed in Fig. 2 is reflected in the monochromatic current–voltage characteristics (@0.1kW/cm2).

Graphic Jump LocationF4 :

With the field-induced extension of the band edge to lower energies, the emission is also redshifted.

Graphic Jump LocationF5 :

The characteristics of the radiative dark current show a tunnel enhancement of the ideality factor, which decreases as the field is reduced.

Graphic Jump LocationF6 :

Local density of states of a 20-period quantum well superlattice at vanishing bias voltage and (a) flat band conditions, corresponding to an intrinsic system, and (b) for a doping density of 2×1018cm3. Although the effective bandgap is increased as compared with bulk InGaAs because of confinement, the strong coupling results in a pronounced carrier delocalization and associated quasi-3D DOS.

Graphic Jump LocationF7 :

Current voltage characteristics of the 20-period superlattice in the dark and under monochromatic illumination with photons of 0.95 eV and at 0.1kW/cm2. Because of the high degree of delocalization, the carrier escape probability is unity, i.e., the light JV-curve is the exact superposition of the bias-dependent photocurrent from the absorptance and the radiative dark current.

Graphic Jump LocationF8 :

JV characteristics, integral and spectral current flow at (a) short-circuit conditions (0 V), (b) close to the maximum power point (0.45 V), (c) at open-circuit conditions (0.52 V), and (d) at open-circuit voltage in the dark. Although the minibands break up under realistic built-in fields, carrier extraction proceeds almost ballistically for thin barriers.

Graphic Jump LocationF9 :

Photocurrent spectrum (0.1kW/cm2@0.95 eV) of coupled quantum well absorber structures with fixed InGaAs QW size of 2.5 nm and InAlGaAs layer thicknesses ranging from 1.5 to 3.5 nm. With increasing barrier width, the character of carrier transport gradually changes from quasi-ballistic to phonon-assisted sequential tunneling.

Graphic Jump LocationF10 :

(a) Local density of states in a double quantum well tunnel junction, (b) associated local absorption coefficient, and (c) the overall absorptance of the structure, revealing pronounced deviations from the flat band situation of a square well potential and bulk injection regions.

Tables

Table Grahic Jump Location
Table 1Material parameters for the two-band effective mass model used for the simulation of the ultra-thin film and quantum well superlattice absorbers.

References

Aeberhard  U., Morf  R. H., “Microscopic nonequilibrium theory of quantum well solar cells,” Phys. Rev. B. 77, (12 ), 125343  (2008). 1098-0121 CrossRef
Aeberhard  U., “Theory and simulation of photogeneration and transport in Si-SiOx superlattice absorbers,” Nanoscale Res. Lett.. 6, , 242  (2011). 1556-276X CrossRef
Aeberhard  U., “Effective microscopic theory of quantum dot superlattice solar cells,” Opt. Quantum Electron.. 44, (3–5 ), 133 –140 (2012). 0306-8919 CrossRef
Aeberhard  U. et al., “Fluorescence of colloidal PbSe/PbS QDs in NIR luminescent solar concentrators,” Phys. Chem. Chem. Phys.. 14, (47 ), 16223 –16228 (2012). 1463-9076 CrossRef
Aeberhard  U., “Theoretical investigation of direct and phonon-assisted tunneling currents in InAlGaAs/InGaAs bulk and quantum-well interband tunnel junctions for multijunction solar cells,” Phys. Rev. B. 87, (8 ), 081302  (2013). 1098-0121 CrossRef
Aeberhard  U., “Simulation of absorption, photogeneration, and carrier extraction in nanostructure-based and ultra-thin film solar cell devices beyond the classical picture,” Proc. SPIE. 8981, , 898103  (2014). 0277-786X CrossRef
Aeberhard  U., “Theory and simulation of quantum photovoltaic devices based on the non-equilibrium Green’s function formalism,” J. Comput. Electron.. 10, (4 ), 394 –413 (2011). 1569-8025 CrossRef
Aeberhard  U., “Quantum-kinetic theory of photocurrent generation via direct and phonon-mediated optical transitions,” Phys. Rev. B. 84, (3 ), 035454  (2011). 1098-0121 CrossRef
Aeberhard  U., “Photon Green’s functions for a consistent theory of absorption and emission in nanostructure-based solar cell devices,” Opt. Quantum Electron.. 46, (6 ), 791 –796 (2014). 0306-8919 CrossRef
Mahan  G., “Quantum transport equation for electric and magnetic fields,” Phys. Rep.. 145, (5 ), 251 –318 (1987). 0370-1573 CrossRef
Massiot  I. et al., “Nanopatterned front contact for broadband absorption in ultra-thin amorphous silicon solar cells,” Appl. Phys. Lett.. 101, (16 ), 163901  (2012). 0003-6951 CrossRef
Wang  Z., White  T. P., Catchpole  K., “Plasmonic near-field enhancement for planar ultra-thin photovoltaics,” IEEE Photon. J.. 5, (5 ), 8400608  (2013).CrossRef
Green  M. A., “Potential for low dimensional structures in photovoltaics,” Mat. Sci. Eng. B. 74, (1–3 ), 118 –124 (2000). 0921-5107 CrossRef
Fujii  H. et al., “100-period, 1.23-eV bandgap InGaAs/GaAsP quantum wells for high-efficiency GaAs solar cells: toward current-matched Ge-based tandem cells,” Prog. Photovolt: Res. Appl.. 22, (7 ), 784 –795 (2014). 1062-7995 CrossRef
Kirchartz  T. et al., “Efficiency limits of Si/SiO2 quantum well solar cells from first-principles calculations,” J. Appl. Phys.. 105, (10 ), 104511  (2009). 0021-8979 CrossRef
Courel  M., Rimada  J. C., Hernández  L., “GaAs/GaInNAs quantum well and superlattice solar cell,” Appl. Phys. Lett.. 100, (7 ), 073508  (2012). 0003-6951 CrossRef
Lumb  M. P. et al., “Double quantum-well tunnel junctions with high peak tunnel currents and low absorption for InP multijunction solar cells,” Appl. Phys. Lett.. 100, (21 ), 213907  (2012). 0003-6951 CrossRef

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