Paper
17 September 2007 Improving the dye-sensitized solar cell
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Abstract
Two dye sensitized solar cells (DSC) can be joined to form a tandem cell with two separate absorption ranges for the two different absorber materials. This can enhance the solar conversion efficiency and in particular the photovoltage of the DSC. Water splitting appears as a realistic long term target. The DSC tandem can be realized as n-n junction employing known dye molecules with optimal absorption spectra. Dye molecules with elongated shapes can be realized by covalently attaching a conducting bridge group terminated by an anchor group to a desired chromophore. Due to the long conducting bridge group separating the hole state of the dye from the surface of the semiconductor recombination is slowed down. The ordered molecular structure can be self-assembled on the recently introduced rod or cylinder shaped oxide electrodes but will not slow down recombination in the nm-cavities of the conventional TiO2 Graetzel electrode.
© (2007) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Frank Willig "Improving the dye-sensitized solar cell", Proc. SPIE 6643, Physical Chemistry of Interfaces and Nanomaterials VI, 66430F (17 September 2007); https://doi.org/10.1117/12.734025
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KEYWORDS
Dye sensitized solar cells

Molecules

Absorption

Bridges

Chromophores

Semiconductors

Interfaces

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