Systematization of published spectral data on deuterated isotopologues of hydrogen sulfide molecule

S. S. Voronina; O. V. Naumenko; E. R. Polovtseva; A. Z. Fazliev

doi:10.1117/12.2075976

25 November 2014 Systematization of published spectral data on deuterated isotopologues of hydrogen sulfide molecule

S. S. Voronina, O. V. Naumenko, E. R. Polovtseva, A. Z. Fazliev

Proceedings Volume 9292, 20th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics; 92920B (2014) https://doi.org/10.1117/12.2075976
Event: 20th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, 2014, Novosibirsk, Russian Federation

Abstract

The report presents a description of properties of published data on spectral lines parameters of deuterated isotopologues of hydrogen sulfide - HDS, HD³⁴S, D₂S, D₂ ³⁴S. Properties values characterizing data quality are calculated taking into account the validity criteria and credit estimation according to publishing criteria. Formalized criteria of data check based on the constraints and selection rules known from the vibrational-rotational theory, as well as an expert evaluation are utilized for validation of the original experimental transitions and energy levels. The consistent and accurate set of the vibration - rotation (VR) energy levels is derived based on the cleaned transitions. Published vibrational-rotational transitions and energy levels of considered molecules as well as the knowledge base are available in the Internet in W@DIS information system (IS).

Citation Download Citation

S. S. Voronina, O. V. Naumenko, E. R. Polovtseva, and A. Z. Fazliev "Systematization of published spectral data on deuterated isotopologues of hydrogen sulfide molecule", Proc. SPIE 9292, 20th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, 92920B (25 November 2014); https://doi.org/10.1117/12.2075976

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