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Electrochemiluminescence (ECL) is a phenomenon in which light is emitted from the excited state of a redox-active material generated by electrochemical reactions. ECL devices have various advantages in terms of structure and simple fabrication, and they are therefore expected as next generation emitting devices. In this paper, we report that electrochemically triggered upconverted luminescence through triplet–triplet energy transfer (TTET) and subsequent triplet–triplet annihilation upconversion (TTA-UC) is first observed in the electrochemiluminescence properties of a Ru complex/diphenylantracene (DPA) containing electrochemical device. Further, ultra-fast quick response in emission is observed in DNA modified electrode cell.
Norihisa Kobayashi
"Upconverted emission in AC-driven electochemiluminescent device with DNA modified electrodes", Proc. SPIE PC12741, Advanced Materials, Biomaterials, and Manufacturing Technologies for Security and Defence, PC1274102 (17 October 2023); https://doi.org/10.1117/12.2680453
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Norihisa Kobayashi, "Upconverted emission in AC-driven electochemiluminescent device with DNA modified electrodes," Proc. SPIE PC12741, Advanced Materials, Biomaterials, and Manufacturing Technologies for Security and Defence, PC1274102 (17 October 2023); https://doi.org/10.1117/12.2680453