CONFERENCE PROCEEDINGS
Advanced Search
Home > Proceedings > Volume 0553 > Article
Paper
20 December 1985 Vibrational Analysis of 1H-labelled Propanes In The 11500 to 100 cm-1 Spectral Region
K. M. Gough, F. L. Baudais, H. L. Casal
Author Affiliations +
Proceedings Volume 0553, Fourier and Computerized Infrared Spectroscopy; (1985) https://doi.org/10.1117/12.970875
Event: 1985 International Conference on Fourier and Computerized Infrared Spectroscopy, 1985, Ottawa, Canada
Abstract
The gas phase infrared spectra of specifically 1H-labelled propanes CHD2CD,CD, and CD3CHDCD3 together with the spectrum of CD3CD2CD3 have been measured between 11500 and 500 cm 1. Assignments of these spectra in the fundamental and overtone regions are proposed. The Raman spectra between 100 and 3000 cm-1 of the same compounds are also reported; they are necessary to give the full view of the vibrational spectrum at the fundamental level. The major spectral features of the overtone spectral region can be explained on the basis of coupling between overtones of C-H stretching vibrations and CHD deformation vibrations. Fermi resonance coupling interactions between the two types of overtones are stronger with increasing overtone number. The present results show that there is an effect on isolated C-H stretching frequencies due to deuterium substitution.
© (1985) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Citation Download Citation
K. M. Gough, F. L. Baudais, and H. L. Casal "Vibrational Analysis of 1H-labelled Propanes In The 11500 to 100 cm-1 Spectral Region", Proc. SPIE 0553, Fourier and Computerized Infrared Spectroscopy, (20 December 1985); https://doi.org/10.1117/12.970875
ACCESS THE FULL ARTICLE
ORGANIZATIONAL
Sign in with credentials provided by your organization.
INSTITUTIONAL
Select your institution to access the SPIE Digital Library.
SELECT YOUR INSTITUTION
PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.
PERSONAL SIGN IN
No SPIE Account? Create one
PURCHASE THIS CONTENT
SUBSCRIBE TO DIGITAL LIBRARY
50 downloads per 1-year subscription
Members: $195
Non-members: $335 ADD TO CART
25 downloads per 1 - year subscription
Members: $145
Non-members: $250 ADD TO CART
PURCHASE SINGLE ARTICLE
Includes PDF, HTML & Video, when available
Members: $17.00
Non-members: $21.00 ADD TO CART
PROCEEDINGS
 2 PAGES
DOWNLOAD PAPER SAVE TO MY LIBRARY
GET CITATION
Advertisement
Advertisement
RIGHTS & PERMISSIONS
Get copyright permission  Get copyright permission on Copyright Marketplace
KEYWORDS
Infrared radiation
Critical dimension metrology
Raman spectroscopy
Analytical research
Chemistry
Infrared spectroscopy
RELATED CONTENT
Subscribe to Digital Library
Receive Erratum Email Alert
Back to Top