Photoionization Of Small Molecules Using Synchrotron Radiation

T A Ferrett; A C Parr

doi:10.1117/12.945470

11 July 1988 Photoionization Of Small Molecules Using Synchrotron Radiation

T A Ferrett, A C Parr

Proceedings Volume 0911, X-Ray and Vacuum Ultraviolet Interaction Data Bases, Calculations, and Measurements; (1988) https://doi.org/10.1117/12.945470
Event: 1988 Los Angeles Symposium: O-E/LASE '88, 1988, Los Angeles, CA, United States

Abstract

We report here new high-resolution vibrationally resolved studies of photoionization in the molecules CO and CO₂ using synchrotron radiation in the photon-energy range 10-30 eV. The detailed decay dynamics of autoionizing resonances in CO and the origin of symmetry-forbidden vibrational transitions in the C state of CO2+ are discussed. These examples illustrate the need for experimental work with both high optical resolution and electron resolution sufficient to resolve the complex resonances in molecules and the vibrational dependence of molecular dynamics.

Citation Download Citation

T A Ferrett and A C Parr "Photoionization Of Small Molecules Using Synchrotron Radiation", Proc. SPIE 0911, X-Ray and Vacuum Ultraviolet Interaction Data Bases, Calculations, and Measurements, (11 July 1988); https://doi.org/10.1117/12.945470

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