Complexes Between HC1 And Proton Acceptors In Low Temperature Argon Matrices And In Gas Mixtures

W. O. George; Rh. Lewis

doi:10.1117/12.969568

1 December 1989 Complexes Between HCl And Proton Acceptors In Low Temperature Argon Matrices And In Gas Mixtures

W. O. George, Rh. Lewis

Proceedings Volume 1145, 7th Intl Conf on Fourier Transform Spectroscopy; (1989) https://doi.org/10.1117/12.969568
Event: Seventh International Conference on Fourier and Computerized Infrared Spectroscopy, 1989, Fairfax, VA, United States

Abstract

The FT-IR spectra of mixtures of argon, ethene, ethyne, d6-benzene, fluorobenzene, CO, CO2, SO2, CCl4, CHC13, d6-acetone, ethanol, HCN, and Acrylonitrile in mixtures with HC1 have been recorded as gases and by matrix isolation. The features which are measured are: 1. The changes in the integrated intensity of lines in the rotation-vibration spectrum of the fundamental HC1 band as a function of nonspecific interactions with other components of the mixture. 2. Bands associated with specific interactions forming hydrogen bonded complexes in the gas and matrix isolated phase. The relationship between the two kinds of interactions is discussed.

Citation Download Citation

W. O. George and Rh. Lewis "Complexes Between HCl And Proton Acceptors In Low Temperature Argon Matrices And In Gas Mixtures", Proc. SPIE 1145, 7th Intl Conf on Fourier Transform Spectroscopy, (1 December 1989); https://doi.org/10.1117/12.969568

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