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Using Z-scan and femtosecond 2.35-µm pulses, we study high-order nonlinear effects – multiphoton absorption (MPA) and nonlinear refraction (n2) in several notable mid-IR nonlinear monocrystals. We find that the multiphoton absorption orders N vary from N=4 (GaSe, ZGP) to N=6 (GaP, ZnSe) and correspond to the crystals’ bandgaps.
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Konstantin L. Vodopyanov, Peter G. Schunemann, Taiki Kawamori, "Mid-IR high-order multiphoton absorption and nonlinear refraction in GaP, ZnSe, GaSe, and ZGP crystals," Proc. SPIE 11910, Laser-Induced Damage in Optical Materials 2021, 1191008 (15 October 2021); https://doi.org/10.1117/12.2601661