Photoresponsive polymers containing side-chain chiral azocarbazole chromophores as multifunctional materials

Renato Bozio; Tiziano Dainese; Loris Giorgini; Attilio Golemme; Francesco Mauriello; Danilo Pedron; Roberto Termine

doi:10.1117/12.767513

13 September 2007 Photoresponsive polymers containing side-chain chiral azocarbazole chromophores as multifunctional materials

Renato Bozio, Tiziano Dainese, Loris Giorgini, Attilio Golemme, Francesco Mauriello, Danilo Pedron, Roberto Termine

Author Affiliations +

Proceedings Volume 6653, Linear and Nonlinear Optics of Organic Materials VII; 665305 (2007) https://doi.org/10.1117/12.767513
Event: Photonic Devices + Applications, 2007, San Diego, California, United States

Abstract

A new optically active photochromic polymethacrylate containing the carbazole moiety, deriving from the chiral monomer (S)-(4-cyanophenyl)-[3-[9-[2-(2-methacryloyloxypropanoyloxy) ethyl]carbazolyl]]diazene [(S)-MLECA] has been prepared and fully characterized with the aim to obtain a multifunctional material which can be considered at the same time as a photonic material for NLO and optical storage, for chiroptical switches, and for photorefractive and photoconductive applications. The complete reversibility of the photoinduced linear birefringence, which is related to fatigue resistance properties seems to be promising for use in optical storage or more generally in the field of photoresponsive systems, and it is not necessary to add dopants in order to observe photoconduction thanks to the presence of the carbazole moiety, which is well known for its hole conducting properties.

Citation Download Citation

Renato Bozio, Tiziano Dainese, Loris Giorgini, Attilio Golemme, Francesco Mauriello, Danilo Pedron, and Roberto Termine "Photoresponsive polymers containing side-chain chiral azocarbazole chromophores as multifunctional materials", Proc. SPIE 6653, Linear and Nonlinear Optics of Organic Materials VII, 665305 (13 September 2007); https://doi.org/10.1117/12.767513

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

;

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE