A new imprint directed self-assembly (DSA) route is developed for creating high resolution line patterns consisting of in-plane polystyrene-block-polydimethylsiloxane (PS-b- PDMS) cylinders. Resist line prepatterns are prepared by nanoimprint and trimmed by oxygen plasma to proper feature geometry and dimension. Registered block copolymer line patterns with exceptional long-range order are generated after DSA then, with the smallest half-pitch of 6 nm or so. Excellent stretching capability of PS-b-PDMS polymer chains indicates a broad process window for DSA. Initial pattern transfer results at 16.5 nm pitch imply the potential of this approach for future nanodevice fabrication at ultra-high pattern resolution.
Directed self-assembly (DSA) of block copolymers (BCPs) proves to be a viable solution for the ultrahigh density bit-patterned media (BPM) application. However, servo design integration is still extremely challenging since the servo layouts require more complex patterns than the simple arrays naturally achieved by the DSA process. We present an integration scheme to create BPM servo patterns by utilizing the BCP dot-array patterns. This proposed method is based on an imprint guided two-step DSA process, combined with conventional optical lithography to define two separate zones. Both the data zone and servo zone consist of self-assembled hexagonal dot arrays: a regular pattern in the data zone and an arbitrary pattern in the servo zone. This method was successfully used to fabricate a servo-integrated BPM template with an areal density of 1.5 Teradot/inch2 (Td/in.2) (Lo=22.3 nm). Using the fabricated quartz template, CoCrPt BPM media has been successfully patterned by nanoimprint lithography and subsequent ion-beam etching process on a 2.5 in. disk. Further, using patterned-in servo wedges on 1.5 Td/in.2 patterned CoCrPt media, we are able to close the servo control loop for track-following on a spin-stand test. The standard deviation of repeatable run-out over the full revolution is calculated to be about 4% of the 38.6 nm track pitch. This method is currently being used to fabricate a template at a much higher density of 3.2 Td/in.2 (Lo=15.2 nm).
Bit-patterned media (BPM) fabrication sets a high bar for nanopatterning especially in the aspects of lithography resolution and pattern transfer. Directed self-assembly (DSA) of spherical block copolymers (BCPs) provides promising pattern resolution extendibility and pattern layout flexibility as long as proper pre-pattern designs are provided. Polystyrene-block-polydimethylsiloxane in the form of monolayered spheres is used as a vehicle to form either globally densely packed nanodot arrays in the data zone or locally densely packed nanodot arrays in the servo zone on a BPM template. Skew compatibility of spherical BCPs is also discussed. The BCP dot template is then applied as the scaffold for pattern transfer into quartz to make a nanoimprint mold and further into magnetic storage media. Distributions of both dot sizes and dot spacings are closely monitored after DSA pattern formation and pattern transfer.
We studied the erosion and feature stability of fused silica patterns under different template cleaning conditions. The conventional sulfuric acid and hydrogen peroxide mixture (SPM) cleaning is compared with an advanced nonacid process. Spectroscopic ellipsometry optical critical dimension measurements were used to characterize the changes in pattern profile with good sensitivity. This study confirmed the erosion of the silica patterns in the traditional acid-based SPM cleaning mixture (H 2 SO 4 +H 2 O 2 ) at a rate of ∼0.1 nm per cleaning cycle. However, the advanced nonacid cleaning process only showed critical dimension shift of ∼0.01 nm per cleaning. Contamination removal and pattern integrity of sensitive 20-nm features under MegaSonic assisted cleaning was also demonstrated.
We studied the erosion and feature stability of fused silica patterns under different template cleaning conditions. The
conventional SPM cleaning is compared with an advanced non-acid process. Spectroscopic ellipsometry optical
critical dimension (SE-OCD) measurements were used to characterize the changes in pattern profile with good
sensitivity. This study confirmed the erosion of the silica patterns in the traditional acid-based SPM cleaning mixture
(H2SO4+H2O2) at a rate of ~0.1nm per cleaning cycle. The advanced non-acid clean process however only showed
CD shift of ~0.01nm per clean. Contamination removal & pattern integrity of sensitive 20nm features under
MegaSonic assisted cleaning is also demonstrated.
KEYWORDS: Scanning electron microscopy, Image processing, Image analysis, Metrology, Line width roughness, Critical dimension metrology, Monte Carlo methods, Transmission electron microscopy, Quartz, Process modeling
Critical dimension metrology is the most needed feedback in nanofabrication and automatic CDSEM-based methods
are by far the industrial standard for its well-established methodology and ease of programming and flexibility in
measurement setup and operation. The dimensional measurements from SEMs consist of two steps, the first being the
pixel based electron emission signal intensity profile generation and the second being the algorithm treatment on the
generated intensity profile for the dimension determination. However, SEM metrology involves uncertainty of the
measurement in the signal processing step, because the SEM signal formation is an extremely complex process
depending on the pattern geometry, materials, detector setup, and beam voltage. Analytical SEMs are even less
optimized for the task of quantitative metrology, especially at the CD ranging below 100 nm.
In this work, we used an analytical SEM for CD metrology applications on quartz nanoimprint template from the
perspective that only analytical SEM is accessible. The machine was tuned and beam characterization was done first to
find the best reasonable condition for consistent manual operation using BEAMETR beam measurement pattern and
software. The optimized beam condition set was then used for image collection on pitch pattern quartz template and
the measurements were done using regular imaging processing and physical model based processing tool myCD. In
order to discuss the spot size on the scan signal and the resulting influence on CD measurements, we used CHARIOT
simulation software for simulated intensity profile as demonstration. The quartz template was then measured through a
mask CDSEM for final data comparison. Selected sites were cross sectioned to reveal profile information as metrology
comparison reference. Through our exercise, the metrology capability and fundamental limitation of analytical SEM
operation with regular imaging processing was identified and the improvement using the physical modeling imaging
process was verified.
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