Planar polycrystalline laser waveguides with the structure YAG/Yb:YAG/YAG were produced by ceramic processing. Transparent ceramics represent a valid alternative to single crystals as the flexibility of the ceramic process paves the way to new application opportunities. The implementation of different ceramic shaping techniques allows the production of complex or multicomponent (composite) structures that are generally difficult or about impossible to obtain with single crystals. A practical example are the planar structures presented here, characterized by a strict control of the dopant distribution obtained already during the shaping process, without further machining or bonding. The waveguides are composed of a laser active Yb:YAG layer obtained by tape casting with a thickness between 100 and 250 μm placed between dopant-free YAG cladding obtained by oxide powder mixing. The refractive index of Yb:YAG is higher than YAG thus realizing a multimode waveguide. Two types of geometries were tested: 1. simple planar waveguide with a sandwich structure (confinement in one direction); 2. waveguide with a rectangular cross section (confinement in two directions). The waveguides were tested for laser emission in a cavity end pumped by a fiber coupled diode laser, under quasi-CW pumping conditions (rectangular pump pulses with 10 ms duration, 10 Hz), delivering up to 60W at 936 nm. The planar waveguide has shown a maximum output power of 14.4 W (slope efficiency 39.1%, optical efficiency 27.4%) whereas the 2D waveguide had a maximum output power of 11.6 W (slope efficiency 38.4%, optical efficiency 22.4%). Lasing wavelength was 1030 nm.
We report a review on our recent developments in Yttebium and Neodymium doped laser ceramics, along two main research lines. The first is the design and development of Yb:YAG ceramics with non uniform doping distribution, for the management of thermo-mechanical stresses and for the mitigation of ASE: layered structures have been produced by solid state reactive sintering, using different forming processes (spray drying and cold press of the homogenized powders, tape cast of the slurry); samples have been characterized and compared to FEM analysis. The second is the investigation of Lutetium based ceramics (such as mixed garnets LuYAG and Lu2O3); this interest is mainly motivated by the favorable thermal properties of these hosts under high doping. We recently obtained for the first time high efficiency laser emission from Yb doped LuYAG ceramics. The investigation on sesquioxides has been focused on Nddoped Lu2O3 ceramics, fabricated with the Spark Plasma Sintering method (SPS). We recently achieved the first laser emission above 1 W from Nd doped Lu2O3 ceramics fabricated by SPS.
Yb:YAG ceramic solid-state laser gain media have been of growing interest for high-repetition rate and high-power lasers during the last few years. A great advantage of ceramic technology compared with that of single crystals is the flexibility of shaping methods allowing the production of near-net-shape components with a well-defined internal structure. A favorable dopant distribution can enhance laser efficiency by mitigating thermal effects. The presented work reports on Yb:YAG transparent ceramics composed of layers with different Yb doping produced by two different shaping methods: dry pressing of spray-dried powders and tape casting, all sintered under high vacuum. The selected geometry of materials was based on numerical simulations. Optical quality of produced ceramics was characterized and discussed in connection with the microstructure and laser emission results. Output power of nearly 7 W and slope efficiency of 58.1% were obtained in quasi-continuous wave regime from bilayered 0% to 10% Yb:YAG. In the case of multilayered materials, higher scattering losses were observed. The comparison of the two processing methods highlighted that the tape-cast materials provided higher optical uniformity and the diffusion zone between the single layers with different dopant content was about 150 μm compared to about 250 μm in samples produced by pressing of powders.
The use of Yb:YAG ceramic gain media in solid state lasers has been of growing interest for high repetition rate and high power lasers. Probably the most important advantage of ceramic production technology in comparison with that of single crystals is the flexibility of shaping methods that allow the production of near-net-shape components with a welldefined internal structure. In the case of Yb:YAG with dopant distribution designed accordingly to the pumping and cooling geometry the efficiency of the laser device can be enhanced by mitigating thermal lensing effects. The presented work reports on Yb:YAG transparent ceramics composed of layers with different Yb doping produced by two different shaping methods: dry pressing of spray-dried powders and tape casting, all sintered under high vacuum. The selected geometry of materials was based on numerical simulations. Microstructure of the produced materials was characterized by SEM and EDX with a particular attention to the dopant content across the layers. The optical quality of produced ceramics was characterized and discussed in connection with the microstructure and laser emission results. Output power of nearly 7 W and slope efficiency 58.1 % were obtained in QCW regime from bilayered 0-10 %Yb:YAG. In the case of multilayered materials higher scattering losses were observed. The comparison between the two processing methods highlighted that the tape-cast materials provided higher optical uniformity and the diffusion zone between the single layers with different dopant content was about 150 nm compared to about 250 nm in samples produced by pressing of powders.
The laser, optical and spectroscopic properties of multilayer Yb:YAG ceramic structures, differently activated, were investigated. The structures were designed by means of Finite Element Modeling, adjusting the doping distributions to reduce peak temperature, surface deformation and thermally induced stresses, depending on the pump and cooling geometry. Two ceramic processes were used, i.e. dry pressing of spray-dried powders (SD) and tape casting (TC), resulting in different defect density and size distribution: TC gives a more uniform transmission, whereas SD results in larger, unevenly scattered defects. The spectroscopic properties were found independent from the production process. The laser performance has been characterized under high intensity pumping in a longitudinally diode pumped laser cavity, comparing the behavior of the different structures in terms of slope efficiency, stability under increasing thermal load, spatial uniformity of laser emission. Slope efficiency values as high as 58% in Quasi-CW pumping conditions and 54% in CW conditions was measured in two-layers structures. The production process and the number of layers influenced the behavior of the samples, in particular regarding the spatial uniformity of the laser emission. Samples made by tape casting have shown overall a better thermal stability with respect to the samples made by spray drying.
Guido Toci, Antonio Lapucci, Marco Ciofini, Laura Esposito, Jan Hostaša, Andreana Piancastelli, Leonida Gizzi, Luca Labate, Paolo Ferrara, Angela Pirri, Matteo Vannini
Significant improvements in efficiency in high power, high repetition rate laser systems should come from the use of ceramic laser active elements suitably designed to mitigate the thermal and thermo-mechanical effects (TEs and TMEs) deriving from the laser pumping process. Laser active media exhibiting a controlled and gradual distribution of the active element(s) could therefore find useful applications in the laser-driven inertial confinement fusion systems, which are considered among the most promising energy source of the future (ultraintense laser pulses), and in medical applications (ultrashort laser pulses) The present work explores the flexibility of the ceramic process for the construction of YAG (Y3Al5O12) ceramic laser elements with a controlled distribution of the Yb doping, in view of the realization of structures modelled to respond to specific application. Two processing techniques are presented to prepare layered structures with a tailored modulation of the doping level, with the goal of reducing the peak temperature, the temperature gradients and also the thermally-induced deformation of the laser material, thus mitigating the overall thermal effects. Tape casting in combination with thermal compression of ceramic tapes with a varying doping level is one of the presented techniques. To make this process as more adaptable as possible, commercial micrometric ceramic powders have been used. The results are compared with those obtained using nanometric powders and a shaping process based on the subsequent pressing of spray dried powders with a different doping level. Laser performance has been characterized in a longitudinally diode pumped laser cavity. The laser efficiency under high thermal load conditions has been compared to those obtained from samples with uniform doping, and for samples obtained with press shaping and tape casting, under the same conditions.
The microstructure of transparent yttrium-aluminum garnet (YAG) ceramics is characterized using different microstructural descriptors, with special focus on grain size numbers. Both linear and planar grain size numbers are used to describe the dependence of the average grain size on Yb dopant content (0-10 at.%), sintering additive (tetraethyl orthosilicate, TEOS) content (0.3-0.5 wt.%) and firing time. Although the two grain size numbers are very close for the materials studied (with ratios very close to unity, around 0.987 ± 0.109), these two numbers are principally independent and provide complementary microstructural information. Their relations to other microstructural descriptors (interface density, mean curvature integral density, mean chord length, Jeffries size) are discussed throughout the text. It is found that Yb doping of more than 3 at.% has a grain-growth-inhibiting effect (after sufficiently long firing times), but differences in the TEOS content between 0.3 and 0.5 wt.% do not have any sensible effect. The largest effect on the microstructure is exerted by the firing time (with prolonged firing times leading to grain growth), but with higher Yb doping the effect of firing time on the grain size becomes less pronounced: for YAG samples without Yb doping, increasing the firing time by a factor of 8 (from 2 h to 16 h), deceases the grain size number by 33.2-35.0 %, whereas with a Yb dopant content of 10 at.%, the corresponding decrease in the grain size number is only 8.7-10.0 %. These findings are fully corroborated using the other microstructural descriptors.
Slabs with non-uniform doping distribution are studied with the aim of reducing thermal deformations in high-energy high-average-power Yb:YAG slab systems. We present a numerical analysis based on Finite Element Mesh (FEM) methods suitable to model non-uniform devices. The thermal variation of the refractive index, the end-faces deformations and the photo-elastic effect have been calculated in order to estimate the total thermal-lens effect. The stress distributions are also obtained. Some results of this numerical approach are compared to experimental thermal lens measurements in a simple geometry for both uniform and structured samples, in order to validate the numerical procedures. Finally we compare numerical simulations for different single- or double-sided pumping and cooling geometries. They show that structured slabs can reduce thermal gradients with respect to uniformly doped means with comparable absorption and geometry. This means a reduction of thermal lens effect and thus an increase of maximum allowed pump power loading. Previous literature reports some work made with structured slabs where higher doping was located in layers with lower pump radiation levels, in order to get a more uniform absorption. Interestingly our modeling indicates that reduced thermal effects are instead obtained when a higher doping is located close to the cooled surfaces.
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